Heat capacity and phase equilibria of wadeite-type K2Si4O9     

Wenjun Yong  E. Dachs  A. C. Withers  E. J. Essene 《Contributions to Mineralogy and Petrology》2008,155(2):137-146

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Assessment of disaster resilience capacity of hillslope communities with high risk for geological hazards   总被引：2，自引：0，他引：2  

Su-Chin Chen  Jhy-Wei Ferng  Yu-Ting Wang  Ting-Yeh Wu  Jieh-Jiuh Wang   《Engineering Geology》2008,98(3-4):86-101

This study presents a novel preparedness assessment method for assessing hazard mitigation and environmental planning of hillslope communities. A professional questionnaire was utilized to weight each indicator. Communities in Hsinchu, Taichung and Nantou counties with debris flow hazards were taken as study samples. Debris flow risk and landslide susceptibility for each community were determined using Geographic Information System (GIS) technology and logistic regression analysis. Thus, a novel risk assessment method for evaluating disaster resilience capacity of hillslope communities was established. This method was then applied to assess casualties caused by Typhoon Herb in 1996 and Typhoon Mindulle in 2004. Additionally, the analytical results generated by this assessment method were discussed with the aim of developing references for implementation of risk analysis, increasing the effectiveness of disaster mitigation, and reducing future loss of life and property.  相似文献   

Interference of Multiple Strip Footings on Sand Using Small Scale Model Tests   总被引：2，自引：1，他引：1  

Jyant Kumar  Manas Kumar Bhoi 《Geotechnical and Geological Engineering》2008,26(4):469-477

By using small scale model tests, the interference effect on the vertical load-deformation behavior of a number of equally spaced strip footings, placed on the surface of dry sand, was investigated. At any stage, all the footings were assumed to (i) carry exactly equal magnitude of load, and (ii) settle to the same extent. No tilt of the footing was permitted. The effect of clear spacing (s) among footings on the results was explored. A new experimental setup was proposed in which only one footing needs to be employed rather than a number of footings. The bearing capacity increases continuously with decrease in spacing among the footings. The interference effect becomes further prominent with increase in soil friction angle. In contrast to an increase in the bearing capacity, with decrease in spacing of footings, an increase in the footing settlement associated with the ultimate state of shear failure was observed. The present experimental observations were similar to those predicted by the available theory, based on the method of characteristics. As compared to the theory, the present experimental data, however, indicates much greater effect of interference especially for larger spacing among footings.  相似文献   

青岛奥运水域主要污染物环境容量的预测     

徐艳东  娄安刚  谭海涛  龙绍桥  石晓勇 《海洋科学》2006,30(2):38-42

通过对青岛奥运水域现场调查和资料分析,确定了奥运水域污染物的主要来源和主要污染物,然后在潮流模拟的基础上,利用物质输运方程数值模拟了2000~2003年污染物浓度的空间分布,其结果与现状调查基本吻合。最后再利用该输运方程,预测了奥运帆船水域的化学需氧量(COD)、氨氮(NH4 -N)、总磷(TP)的环境容量(中潮时分别为:69.948 t/d,7.46 t/d,0.5455 t/d),为奥运水域的目标管理提供科学依据。  相似文献   

福建泉州湾贝类养殖容量评估   总被引：10，自引：0，他引：10  

卢振彬  杜琦  许翠娅  钱小明  方明杰  蔡清海 《热带海洋学报》2005,24(4):22-29

通过对泉州湾叶绿素a、初级生产力、生态效率、浮游植物有机碳含量、养殖贝类有机碳含量及其含壳重与鲜组织重比值、潮间带和潮下带及吊养区附着滤食性动物现存量等的调查和检测,应用营养动态模型、沿岸能流模型估算贝类生态容量及扣除野生滤食性动物现存量来估算贝类养殖容量。还采用方建光模型估算贝类养殖容量,并采用统计分析法估算贝类及其各品种的适养面积。3种模型估算的贝类养殖容量分别为43 171t、220 991×104个,46 388 t、237 464×104个,44 049t、225 490×104个。贝类适养总面积为2 878hm2,其中牡蛎Ostrea1 349hm2,缢蛏Sinoncvacula con-stricta1 268 hm2,菲律宾蛤仔Ruditapes philippinarum117hm2,翡翠贻贝Perna viridis144hm2。1999年实际养殖面积2 615 hm2,尚有263 hm2可扩大养殖面积。还讨论了模型的实用性等问题。  相似文献   

浙江西沪港重金属铜的配位容量和形态分析   总被引：3，自引：2，他引：3       下载免费PDF全文

吕海燕  王正方  傅和芳  冯旭文 《海洋学报》2003,25(3):47-52

根据2000年6月10～14日在浙江省西沪港采集的海水样品,利用AA-800石墨炉原子吸收分光光度技术和阳极溶出伏安法测定样品中重金属铜的含量,获得铜在海水中受不同的有机配体控制.不同粒级的铜表观配位容量表明西沪港海水过孔径1.00μm微孔膜的(ACuCC)较高,为144.4nmol/dm3;过0.40和0.20μm滤膜的(ACuCC)分别为103.0和102nmol/dm3;铜的有机配体条件稳定常数的对数值在7.25～9.14之间.铜的总量为21.72nmol/dm3.铜全部为稳定溶解态,其中pH2酸溶态占95.0%,强有机结合态占5.0%.溶解态铜中有机结合态占过滤海水中总铜的61.6%.  相似文献   

珠江口水体中铜与悬浮颗粒物相互作用的研究     

丘耀文  王肇鼎  张正斌  刘莲生 《热带海洋学报》1995,(4)

使用无机离子交换法研究珠江口水体中铜与悬浮颗粒物的相互作用，测出钢与悬浮颗粒物相互作用的ｐＨ曲线呈Ｓ形，其分级离子交换等温线是一种新的“台阶”型；从分级离子交换理论求得分级平衡常数Ｋ１为５．０，Ｋ２为７８．１，珠江口水体中铜的表观络合容量为０．９２μｍ及其条件稳定常数为３．５×１０７。  相似文献   

Behavior of Pile Groups under Lateral Load   总被引：2，自引：0，他引：2  

Yang Keji  Li Qixin Wang Fuyuan Associate Proferssor  Hehai University  Nanjing Engineer  Hehai University  Nanjing 《中国海洋工程》1991,(2)

Based on investigation and model tests, and in combination with the research work on group effect for pile groups under lateral loads relating to the code of fixed offshore platforms, a series of studies have been performed on the behavior and failure mechanism of laterally loaded pile groups, critical pile spacing inducing group effect, lateral bearing capacity of pile groups and its main influence factors, the stress-strain relationship for single piles and pile groups and so on. Some new laws about non-uniformity of load distribution in the longitudinal direction of pile groups and load-deflection (p - y) curves for pile groups have been discovered, and an empirical formula is presented in order to remedy the defect of current calculating methods at home and abroad. These results can be used for reference in the design of pile foundation under lateral loads.  相似文献   

Estimation of Axial Pile Bearing Capacity According to Shear Strength Parameters of Soil     

Yu Xiaodong  Yan Shuwang Sun Wanhe Postgraduate Student  Tianjin University  Tianjin Professor  Tianjin University  Tianjin Senior Engineer  Tianjin Port Engineering Institute  Tianjin 《中国海洋工程》1997,(2)

At pesent,it is very popular to estimate pile bearing capacity by use of empirical formula andphysical indexes of soil provided in the design codes for civil construction in China.This paper attempts toapply mechanical indexes of soil and semi-empirical formulas,which are based on soil mechanical theoriesand were summarized and presented by Meyerhof in 1976,to calculate the axial pile bearing capacity.Lo-ading test results of 24 single piles in Tianjin area have been collected and compared with the proposed cal-ulation approach.  相似文献   

东山湾贝类养殖容量的估算   总被引：6，自引：0，他引：6  

卢振彬  杜琦  钱小明  方民杰  蔡清海  许翠娅 《台湾海峡》2001,20(4):462-470

以初级生产力为基础，应用营养动态模式和沿岸海域能流分析模型，估算东山湾贝类年生产量分别为269331t和295767t，平均282549t。扣除潮间带、潮下带和吊养区浮筏、随着基及延绳上附着的非养殖滤食性附着动物自然现存量35760t，贝类可养殖量为246789t。应用统计分析和逻辑斯谛种群增长模型估计贝类可养面积为11839hm^2，其中缢蛏635hm^2，石蛎1160hm^2,吊蛎1525hm^2，翡翠贻贝633hm^2，菲律宾蛤仔1154hm^2，扇贝698hm^2，江瑶248hm^2，泥蚶601hm^2，巴非蛤4151hm^2，凸壳肌蛤1034hm^2。1998年实际养殖面积和养殖产量分别为10581hm^2和220564t。尚有1258hm^2,26225t的扩大开发潜力。文中还讨论了合理布局和优化养殖结构问题。  相似文献